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Conservation and restoration of metals











Conservation and restoration of metals




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Derveni krater, bronze, 350 BC, height: 90.5 cm (35 ½ in.), Inv. B1, Archaeological Museum of Thessaloniki, after cleaning and conservation.


Conservation and restoration of metals is the activity devoted to the protection and preservation of historical (religious, artistic, technical and ethnographic) and archaeological objects made partly or entirely of metal. In it are included all activities aimed at preventing or slowing deterioration of items, as well as improving accessibility and readability of them as objects of cultural heritage. Despite the fact that metals are generally considered as the relatively permanent and stable materials, in contact with the environment they deteriorate gradually, some faster and some much slower. This applies especially to archaeological finds.


It is very important that a conservator of metals has knowledge of basic metalworking techniques, history of metalwork, history of art, archaeology, corrosion of metals, scientific research methods, theory and ethics of conservation-restoration.




Contents






  • 1 Metals and alloys commonly used for cultural heritage objects


  • 2 Metals and alloys less commonly used for cultural heritage objects


  • 3 Metalworking techniques


    • 3.1 Basic techniques


    • 3.2 Joining techniques


    • 3.3 Some supplementary techniques


    • 3.4 Surface decoration techniques


    • 3.5 Some contemporary techniques




  • 4 Deterioration of metals


  • 5 Deterioration of materials associated with metals


    • 5.1 Organic materials


    • 5.2 Inorganic materials




  • 6 Metals conservation planning


    • 6.1 Basics


    • 6.2 Research


      • 6.2.1 Identification of metals and alloys


      • 6.2.2 Identification of corrosion processes and products


      • 6.2.3 Identification of materials associated with metals


      • 6.2.4 Identification of technology used to produce objects




    • 6.3 Decision making


    • 6.4 Documentation


    • 6.5 Ethics and ethical problems in metals conservation




  • 7 Conservation


    • 7.1 Preventive conservation


    • 7.2 Interventive conservation


      • 7.2.1 Cleaning


      • 7.2.2 Structural consolidation


      • 7.2.3 Reconstruction of missing parts or surface decoration


      • 7.2.4 Stabilization


      • 7.2.5 Protective Coatings




    • 7.3 Conservation of materials associated with metals


      • 7.3.1 Precious and semi precious stones


      • 7.3.2 Enamels


      • 7.3.3 Niello


      • 7.3.4 Amber


      • 7.3.5 Oriental lacquer - urushi


      • 7.3.6 Coral


      • 7.3.7 Pearls


      • 7.3.8 Mother of pearl


      • 7.3.9 Ivory, bone and antler


      • 7.3.10 Tortoiseshell


      • 7.3.11 Jet


      • 7.3.12 Wood


      • 7.3.13 Textile


      • 7.3.14 Paper


      • 7.3.15 Glass


      • 7.3.16 Ceramics and porcelain


      • 7.3.17 Leather


      • 7.3.18 Plastics


      • 7.3.19 Wax


      • 7.3.20 Plaster






  • 8 Replicas and Copies


  • 9 Storage of metallic heritage objects


  • 10 History of metals conservation


    • 10.1 Important persons




  • 11 Specializations within the profession


  • 12 Training


    • 12.1 US


    • 12.2 Canada


    • 12.3 Mexico


    • 12.4 South America


    • 12.5 Africa


    • 12.6 Australia


    • 12.7 Europe


    • 12.8 Ukraine


    • 12.9 Russian Federation


    • 12.10 India


    • 12.11 Iran


    • 12.12 Pakistan


    • 12.13 Quatar


    • 12.14 Turkey


    • 12.15 Jordan




  • 13 Further reading


    • 13.1 Essential literature


    • 13.2 Some important books on metal conservation in languages other than English


    • 13.3 Important older books and articles


    • 13.4 Articles on metals conservation(gold,tin and pewter,lead,zinc and aluminium)


      • 13.4.1 Gold


      • 13.4.2 Tin and pewter


      • 13.4.3 Zinc


      • 13.4.4 Lead


      • 13.4.5 Aluminium






  • 14 Online magazines


  • 15 Metals conservation blogs


  • 16 Free software that can be used for metals conservation


  • 17 See also


  • 18 References


  • 19 External links


    • 19.1 Articles and presentations


    • 19.2 Download free books


    • 19.3 Download free conference proceedings


    • 19.4 Download free theses




  • 20 Metals conservation video files





Metals and alloys commonly used for cultural heritage objects[edit]




The bronze apoxyomenos, dated to between the 1st and 2nd century BC, found and recovered from Adriatic sea near the small island Vele Oryule, near island Loshiny, Croatia; example of archaeological metals conservation.



  • Gold

  • Silver

  • Copper

  • Bronze

  • Brass

  • Nickel

  • Nickel silver

  • Monel

  • Chromium


  • Iron and Steel


  • Weathering steel (Corten)

  • Stainless steel

  • Titanium


  • Tin and Pewter

  • Lead

  • Zinc

  • Aluminium



Metals and alloys less commonly used for cultural heritage objects[edit]



  • Antimony

  • Magnesium

  • Niobium

  • Palladium

  • Platinum

  • Rhodium

  • Mercury

  • Electrum

  • Tumbaga

  • Shakudo

  • Shibuichi

  • Bidri

  • Hepatizon



Metalworking techniques[edit]




















































































Basic metalworking techniques timeline
cold
hot
hand
machine
earliest use
special remarks
Casting

X
X
X
more than 5700 years old process[1]

Forging
X
X
X
X
more than 7000 years old process

Cutting
X

X
X
antique works up to 1500
chisel, knife or scissors
Filling
X

X
X
1200-1000 BC first bronze files

Piercing
X

X
X
goldsmiths piercing saw not known in antique world, earliest examples not before 1500

Drilling


X
X

Rolling
X
X
X
X

first rolling mills, late 16th and 17th century
Wire drawing
X
X
X
X

twisted strip method, drawplate after 600-800



Basic techniques[edit]



  • Casting

  • Forging

  • Folding

  • Sawing

  • Cutting

  • Bending

  • Drilling

  • Filing (metalworking)

  • Piercing

  • Sanding

  • Polishing



Joining techniques[edit]



  • Soldering

  • Welding

  • Mechanical joining

  • Gluing/cementing



Some supplementary techniques[edit]



  • Repousse

  • Chasing

  • Raising (metalwork)

  • Metal spinning

  • Annealing (metallurgy)



Surface decoration techniques[edit]



  • Enamelling

  • Niello

  • Engraving

  • Etching

  • Granulation

  • Filigree


  • Inlay (Damascening)

  • Mokume gane

  • Pattern welding

  • Plating


  • Chemical coloring of metals (Patination)

  • Heat coloring

  • Combining metals and other materials



Some contemporary techniques[edit]



  • Electroforming

  • Reticulation

  • Anodizing

  • Photoetching

  • Fold-forming

  • Metal clay

  • 3D printing



Deterioration of metals[edit]





Perseus with the Head of Medusa in the Loggia dei Lanzi gallery on the edge of the Piazza della Signoria in Florence; picture taken after the statue's cleaning and restoration.


An essential cause of deterioration is corrosion of metal objects or object deterioration by interaction with the environment. As the most influential factors of deterioration of historical objects should be pointed out as the relative humidity and air pollution while in archaeological objects a crucial role has composition, depth, humidity and amount of gasses in the soil. In cases of marine or fresh water finds the most important factors of decay are the amount and composition of soluble salts, water depth, amount of dissolved gases, the direction of water currents and the role of both microscopic and macroscopic living organisms.[2]



Deterioration of materials associated with metals[edit]


Associated materials deteriorate depending on the origin whether they are organic or inorganic materials. Organic materials usually fail in a relatively short period of time, primarily due to biodegradation. With inorganic materials are these processes considerably longer and more complex. Amount of gases, humidity, depth and composition of soil are very important. In case of salty and sweet water finds essential are amount of gases dissolved in water, depth of water, direction of currents, and microscopic and macroscopic living organisms.



Organic materials[edit]



  • Leather

  • Wood

  • Paper

  • Fur

  • Feathers

  • Textile

  • Bone

  • Horn

  • Tortoiseshell

  • Amber

  • Plant fiber

  • Shell

  • Pearls

  • Ivory

  • Coral

  • Jet (lignite)

  • Plastics



Inorganic materials[edit]



  • Precious and semiprecious stones (Gemstone)

  • Glass

  • Enamel

  • Niello

  • Ceramics

  • Porcelain



Metals conservation planning[edit]



Basics[edit]


As with the conservation and restoration works on any other material, here are the basic tenets of conservation-restoration based on the quality of execution and the best possible preservation of cultural, historical and technological identity and integrity of objects. Minimal intervention, reversibility and repeatability of preferred treatment are essential, as well as the possibility of easy identification of restored parts.[3] Recently non-toxic nature of used materials and procedures becomes important too, both in relation to objects and conservator-restorer as a performer, but also in relation to the environment.



Research[edit]


Nowadays scientific research is an integral part of the metals conservation treatment, at least in highly developed countries.



Identification of metals and alloys[edit]



  • Simple methods - visual examination, spot tests, specific gravity

  • Scientific methods - X-ray fluorescence, XRD, Particle-induced X-ray emission, LIBS, SEM, electrochemical techniques, metallography



Identification of corrosion processes and products[edit]



  • Simple method - visual examination, spot tests


  • The Oddy test - for copper, silver, and lead

  • Scientific methods - xrd, SEM, metallography



Identification of materials associated with metals[edit]



  • Simple methods - visual examination, spot tests, specific gravity

  • Scientific methods - xrf, chromatography,


Raman spectroscopy



Identification of technology used to produce objects[edit]



  • Simple methods - visual examination

  • Scientific methods - metallography, x-ray radiography, x-ray computed tomography



Decision making[edit]


In preparing the strategy of the metals conservation project interdisciplinary approach to the same is essential. It implies the participation of as many experts as is possible, as a minimum, we can take curator (archaeologist, historian, art historian), scientists specialized for corrosion of metallic objects of cultural heritage and the conservator - restorer.



Documentation[edit]


Systematic and well-managed documentation is today an essential prerequisite for quality executed conservation and restoration treatments, including documentation of the state of objects before, during and after treatment. Identification of materials and procedures used to produce object and the results of any scientific research must be part of documentation too. Last but not least- an integral part of the documentation must be a recommendation for further care of object.



Ethics and ethical problems in metals conservation[edit]


The ethical concept of conservation of metal objects in principle is the same as those in other fields of conservation-restoration of cultural heritage.


But there are several specific problems that can only be found in the conservation of metals - problem of heat treatment of archaeological objects, and the problem of radical restoration of historic, mostly technical, but also architectonic objects too.


While in the first case problem is primarily in the destruction of valuable scientific data, in case of the technical, the architectural, and somewhat less often, historical objects problem is that a radically restored items just simulate the original appearance of the object, and so in some ways that objects can be considered even as, more or less successful fakes, which only superficially simulate long-lost or never existing state of object.


According to the above-mentioned, whenever it is possible real historical substance must be preserved. Thoroughly documented and technically professionally executed restoration of objects, must be avoided because such objects must be seen only as freshly painted surrogates of authentic historic substance.


Ethical problems connected with conservation of sacred metallic heritage objects can be included too.[4]



Conservation[edit]



Preventive conservation[edit]



Metallic heritage objects are sensitive to environmental conditions such as temperature, humidity, air pollution and exposure to light and ultraviolet light. They must be protected in a controlled environment where such variables are maintained within a range of damage-limiting levels.


Preventive conservation, also known as collections care, is an important element of museum policy. It is an essential responsibility of members of the museum profession to create and maintain a protective environment for the collections in their care, whether in store, on display, or in transit. A museum should carefully monitor the condition of collections to determine when an artifact requires conservation work and the services of a qualified conservator.



Interventive conservation[edit]



Cleaning[edit]




Conservation of gilt bronze Horses of Saint Mark, (Venice).


The most common procedure in conservation and restoration of metals is the cleaning process. This process can be distinguish between mechanical, chemical, electrochemical, ultrasonic, plasma and laser cleaning. In principle, it is aimed at removing dirt and corrosion products from the surface of a metal object. In many cases archaeology objects only can be cleaned mechanically.
























































































































Metal
Mechanical cleaning
Chemical cleaning
Electrochemical cleaning
Ultrasonic cleaning
Laser cleaning
Plasma cleaning
Gold
X
Acidified thiourea solution 8-10% (carcinogenic compound.)

Sodium thiosulphate 30%


EDTA 10 %[5]


X
X
X

Silver
X
Sodium thiosulphate 30%[6]

Ammonium thiosulphate 15%


Acidified thiourea solution 8-10% (carcinogenic compound.)[7]


EDTA 10 %[8]


X
X
X
X
Copper/copper alloy
X
Ammonium citrate 5%/pH 9[9]

Potassium sodium tartarate 25%[10]


EDTA 4%/pH 10[11]


NaOH 12o g/40 g glycerol/1 l water[12]


X
X
X
X
Iron/steel
X
Ammonium citrate 5%/pH 3,5[13]

Phosphoric acid 10-20%[14]


EDTA 4%/pH 5 - 5,5[15]


X
X
X
X
Tin/pewter
X
Hydrochloric acid 5%[16]

Trisodium phosphate 15%[17]


X



Lead
X?
EDTA 4%/pH 5,5[18]

HCl 5% + ammonium acetate 10%[19]


X


X
Zinc
X
Sulphuric acid 5%[20]

EDTA pH 7[21]
Ammonium chloride 10%[22]


X



Aluminum
X?
Ammonium citrate 5%/pH 7[23]
X
X
X

Titanium

Citric acid 10-25%/ 90 °C[24]




Magnesium

30 g sodium carbonate /30 g trisodium phosphate /1 g synthetic soap /1 l water /80-95 °C temp.,3–20 minutes, pH 11[25]
X



Chromium-plated
X?
47,5 g citric acid/47,5 g sodium gluconate/4,9 g tartaric acid/0.1 g non ionic surfacant/1-10 l water[26]




Nickel-plated
X?
47,5 g citric acid/47,5 g sodium gluconate/4,9 g tartaric acid/0,1 g non ionic surfacant/1-10 l water[27]






Structural consolidation[edit]


Aimed at strengthening of the physical structure of the object, and correcting the shape of the object.



  • Mechanical joining - riveting / tab and slot / overlapping / screws

  • Soldering - soft / hard

  • Welding - oxyacetilene / electric arc / TIG / tack / laser / plasma

  • Gluing/Cementing

  • Reconstructions -in original material - in polymers - *3D printing[28]



Reconstruction of missing parts or surface decoration[edit]


In certain cases, metals conservator must re-create the lost parts of objects or restore original surface decoration. This approach is accurate only if we have an exact documentation or photographs of items in a complete, currently non-existent state that we want to return.


New parts must be clearly and visibly marked and at least they must be minimally different from the original historic material.


If needed, those parts must be easily and completely removable from the object, and with methods which will not harm it.




















































Plating
Paste
Immersion
Electroplating/Brushplating
Leaf/powder
Gold
X*
X*
X*
X
Silver
X*
X*
X*
X
Tin
X*
X*
X*
X
Zinc
X*
X*
X*
X
Nickel
X*
X*
X*
Special paint ( MirraChrome [29]) or special metal foil ( Bare-Metal Foil [30])
Chrome


X*
Special paint ( MirraChrome [31]) or special metal foil ( Bare-Metal Foil [32])

Only cyanide or hexchromate free processes must be used.


Only worn-out spots can be replated.


Replating of entire object must be avoided.



Stabilization[edit]


Focused on slowing of deterioration of objects – in the case of archaeology objects the thorough removal or blocking of chloride salts. In case of the historical objects it is focused on the use of corrosion inhibitors, conversion coatings, rust converters or eventually oxygen free storage.



  • Chloride removal (chemical processes, electrochemical processes)

  • Corrosion inhibitors (benzotriazole, tannin)


  • Rust converters˙


  • Conversion coatings (phosphate conversion coatings, phosphate/tannin, etc.)

  • Oxygen free storage






































Metal
Chloride removal
Stabilization
Silver

benzotriazole[33]

2 mercaptobenzotiazole[34]


Copper/copper alloys
Sodium sesquicarbonate[35]

Electrochemical


benzotriazole[36]

4 methyl imidazole[37]


ammonium sulphide[38]


tannin[39][40]


Iron/steel
alkaline sulphite[41]

NaOH/ethylenediamine[42]


electrochemical


tannin[43]

phosphating[44]


Lead

carboxylates[45][46]
Zinc

benzotriazole[47]

tannin[48]


phosphating


Aluminum
amonnia-ammonium sulphate[49]

electrochemical


tannin[50][51]

phosphating[52]




Protective Coatings[edit]


Still mainly focused on use of clear coats and waxes, in case of technology objects oil coatings can be used too. In general it supports the stabilization process.[53]


  • Clear coats:

Paraloid B-72



durable and non-yellowing acrylic resin, chemically an ethyl methacrylate copolymer. It can be used for conservation of metals. Soluble in acetone, toluene, xylene, Shell Cyclo Sol® 100/Shell Cyclo Sol® 53, Arcosolv® PM/1-Methoxy-2-propanol.[54]


Paraloid B 67


is acrylic resin, chemically it is an isobutyl methacrylate polymer. Soluble in toluene, xylene, acetone, Shell Cyclo Sol® 100/Shell Cyclo Sol® 53, Arcosolv® PM/1-Methoxy-2-propanol and white spirit acetone mixture (90 parts white spirit/10 parts acetone).[55]


Paraloid B 44


is acrylic resin, chemically it is composed of methyl methacrylate and ethyl acrylate copolymer. Soluble in toluene, xylene, acetone. It is used for paints and clear coating for metals. It is ingredient in Incralac metal coating.[56]


Paraloid B 48 N


is acrylic resin, chemically it is copolymer of methyl methacrylate and butyl acrylate. It is used as a clear coating for metals - copper, brass, bronze, and zinc. Soluble in toluene, xylene, methyl ethyl ketone, and acetone[57]


Incralac


is special proprietary clear coat for copper and its alloys. It is based on Paraloid B 44 acryilic resin dissolved in toluene. It contains benzotriazole as copper corrosion inhibitor too.[58]


Nitrocellulose lacquer


is solvent-based lacquer that contain nitrocellulose, a resin obtained from the nitration of cotton and other cellulostic materials.[59] Can be used on silver objects. Frigilene, Agateen No.27 and Perlitol RE 1260 are good brands.


ORMOCER


Organically modified ceramic, also known as ORMOCER (ORganically MOdified CERamic) is a type of coating used in the conservation of metals. ORMOCER was originally developed by the Fraunhofer Society for the Advancement of Applied Research in Munich. While it is still in research phase, ORMOCER is essentially a heteropolysiloxane-based clear coat.[60]


Other used varnishes or lacquers that would be worthwhile to examine:


Pantarol A (German product) – the use of it is mentioned in German literature; according to the manufacturer it is a special acrylic coating for metal [61][62]


Everbrite ProtectaClear Coating, Everbrite Coating (US products) - worthwhile to be tested, according to manufacturer product is easily removable from treated objects [63][64]


Permalac(US product) [65]


  • Waxes:

Renaissance Wax



is a brand of microcrystalline wax polish that is widely encountered in antique restoration and museum curation. Although not appropriate for all materials, it is known to and used by almost every collection. It is also used as a primary finish for cabinetry and furniture. Renaissance wax is also used by reenactors of historic swordsmanship to protect armour and weapons. It is widely recognised that this substance is more protective and longer lasting than oil, especially for swords and helmets that are frequently touched by human hands.


To quote a typical commercial supplier of conservation materials, it is used, to revive and protect valuable furniture, leather, paintings, metals, marble, onyx, ivory etc. Freshens colours and imparts a soft sheen[66]


Cosmolloid 80 H


is refined white microcrystalline wax. It can be used on historical and archaeological metals. Melting point 60–94 °C. Soluble in benzol, ether, chloroform, carbon disulfide, carbon tetrachloride, turpentine, petroleum distillates, and fixed oils; partially soluble in acetone, diacetone alcohol. Main ingredient in Renaissance Wax.


TeCero Wachs 30410


is a German brand of microcrystalline wax.[67]


Dinitrol 4010


is a long-term engine protection proprietary product with heat resistance up to 200 °C. It leaves a firm transparent film with short drying time and good adhesion and flexibility on all metal surfaces, rubber and plastic parts. Dinitrol 4010 is resistant to alkali and acidic solutions. According to some research articles it can be used on metallic heritage objects too[68]


Poligen ES 91 009


is patented wax emulsion (BASF), according to some sources better than Paraloid B 72[69]


  • Oils

-WD 40 / Ballistol / 80 parts white spirit+20 parts fish oil


  • Combinations

-base coat Paraloid B 72 / topcoat Renaissance Wax etc.



Conservation of materials associated with metals[edit]



Precious and semi precious stones[edit]


In principle do not use any solvent, but only distilled water, or a 10% solution of soapwort plant (Saponaria officinalis). You must be Especially careful when working on porous gemstones like malachite, opal, chalcedony, chrysoprase, agate, carnelian, lapis lazuli, jade and turquoise. Special attention requires gemstones combined with colored metal foils, in this case, the liquid does not come into contact with the foil. Do not use ultrasonic cleaning.



Enamels[edit]




Niello[edit]


Nielloed items can be cleaned only mechanically, never try to use chemical cleaning. Black pigment mixed with Paraloid B 72 can be used for reconstruction of missing parts.
Concentrated solution of Paraloid B 72 or B 67 (soluble in white spirit) can be used as reversible glue.



Amber[edit]


Do not clean with solvents, do not use ultrasound, you can use only distilled water, or a mixture of water and ethanol (add up to 0.5% crosslinker).[70] Variety of waxy resin mixtures can be used as glue, depending on the color of amber. You can use 10% solution of Canada balsam in toluene[71] Archaeological material can be cleaned only mechanically.
Soaking in liquid paraffin can be used to consolidate and improve color of amber.[72]
According to one Korean article for consolidation can be used Paraloid B 67 dissolved in xylene (proved more stable than white spirit, usual solvent for B 67)[73] According to one American article as ideal consolidant and adhesive can be used Regalrez 1126[74] Artifacts must be Protected from strong light and high temperatures, low humidity and oscillations in humidity, in the case of metal/amber objects do not to use corrosion inhibitors.[75]



Oriental lacquer - urushi[edit]



Requires a completely different approach than western lacquers. May be found on the Japanese arms and armour. The best approach – leave it to expert for oriental lacquer.[76][77][78] Mixture of 6-8% polyvinyl alcohol and chalk can be used as filling material(Rhoplex WS 24 can be used too).[79] Japanese conservators use traditional techniques, but as Urushi causes allergic reactions, these methods are not recommended. Clean it with an aliphatic hydrocarbon such as white or mineral spirits. Distilled water or saliva (moistened cottonwool swabs) can caused discoloration and should be avoided by the inexperienced: pH is crucial. Keep objects in rooms with controlled humidity and temperature, preferably about 50% RH, and protect them from UV radiation.



Coral[edit]


Can be cleaned with cotton wool swabs soaked in distilled water, or with a mixture of distilled water and ethanol.[80]
Do not use ultrasound. Avoid any contact with acids.



Pearls[edit]


Historical objects can be cleaned using a mixture of 70% ethanol and 30% weak ammonia water (1%). To remove the surface layer that has lost luster you can use 3–5% EDTA, after that step rinse with distilled water, and then with 80% ethanol, then with 90% ethanol, and finally with pure ethanol.[81]
Do not use ultrasound.
Archaeological finds must be treated as soon as possible, preferably after excavation, you can clean them only mechanically, then consolidate with 2% Paraloid B 72, in the case of dry findings (first saturate with solvent in which it is dissolved), in case of damp or wet findings use Rhoplex WS 24 (acrylic dispersion).[82]
Somewhat More recent Russian literature recommends use of bleached beeswax dissolved in white spirit or medical benzine as protective coating. Fish glue mixed with water and alcohol (7/3), with addition of 1% katamine AB as biocide can be used as glue. Nonionogenic detergent 2-3% in a mixture of water and alcohol can be used for cleaning.[83]
Avoid prolonged contact with water, sudden changes in temperature and relative humidity, including strong light or contact with acidic or alkaline solutions (soap water too).



Mother of pearl[edit]



Ivory, bone and antler[edit]




Tortoiseshell[edit]



Jet[edit]


You can clean it with cottonwool swabs soaked in distilled water or soapwort extract (Saponaria officinalis, 50 - 100 grams of dried root per 1 liter of boiling water). Archaeological material can be cleaned only mechanically. Wax/resin mixtures or concentrated solution of Paraloid B 72 (or B 67) can be
used as glue for archaeology objects.[84]



Wood[edit]



Textile[edit]




Paper[edit]



Glass[edit]


Main article Conservation and restoration of glass objects



Ceramics and porcelain[edit]




Leather[edit]



Plastics[edit]




Wax[edit]



Plaster[edit]


Unsealed plaster can be cleaned with soft brush only; never try to use water or water-based cleaning solutions. Sealed plaster can be cleaned with a swab dampened with water or white spirit.[85]



Replicas and Copies[edit]



  • molding (process)

  • casting

  • electroforming


  • 3D printing[86]



Storage of metallic heritage objects[edit]


The items should be stored in rooms that are protected from polluted air, dust, ultraviolet radiation, and excessive relative humidity - ideal values are temperature of 16-20 °C and up to 40% (35-55% according to recent Canadian Conservation Institute recommendations) relative humidity, noting that if metal is combined with organic materials, relative humidity should not be below 45%. Archaeological objects must be stored in rooms (or plastic boxes) with very low relative humidity, or in the case of particularly valuable items in the chambers with nitrogen or argon. Copper or copper alloy objects with active corrosion up to 35% RH. Iron objects with active corrosion 12-15% RH. Shelves in the storerooms must be of stainless steel or chlorine and acetate free plastic or powder coated steel. Wood and wood-based products (Particle board, plywood) must be avoided. Also do not use rubber, felt or wool. When you are handling metal objects, always wear clean cotton gloves. Lighting levels must be kept below 300 lux (up to 150 lux in case of lacquered or painted objects, up to 50 lux in case of objects with light sensitive materials)[87]



History of metals conservation[edit]



Important persons[edit]



  • Gustav Rosenberg

  • William Matthew Flinders Petrie

  • Friedrich Rathgen

  • Alexander Scott

  • Harold Plenderleith

  • Mstislav Vladimirovich Farmakovskiy

  • Albert France-Lanord

  • Robert M. Organ

  • Hanna Jedrzejewska

  • Joachim Szvetnik

  • Otto Nedbal

  • Hermann Born

  • Eduarto Formigli



Specializations within the profession[edit]



  • Conservation of Historical Metal Objects

  • Conservation of Archaeological Metal Objects

  • Conservation of Technological Metal Objects

  • Conservation of Ethnographic Metal Objects

  • Conservation of Architectural Metal Objects

  • Conservation of Metal Sculpture

  • Conservation of Gold and Silversmiths Works

  • Conservation of Arms and Armour



Training[edit]




US[edit]



  • Buffalo State College, Art Conservation Department, objects specialization

  • UCLA/Getty Masters Program - Conservation of Archaeological and Ethnographic Materials

  • Winterthur/University of Delaware Program in Art Conservation, objects specialization

  • New York University, Institute of Fine Arts, Conservation Center, objects specialization.



Canada[edit]



  • Queens University, Art Conservation, objects specialization

  • Fleming College, Collections Conservation and Management



Mexico[edit]


  • Escuela nacional de conservacion, restauracion y museografia, Ciudad de Mexico, Diplomado de Especialización en Patrimonio Metálico


South America[edit]



  • Chile
    • Centro Nacional de Conservacion y Restauracion, Santiago de Chile, objetos arqueológicos, etnográficos e históricos


  • Perú
    • Universidad Nacional Mayor de San Marcos, Escuela academico profesional de Conservación y Restauración


  • Brasil
    • Universidade Federal de Pelotas, Instituto de Ciências Humanas, Laboratório Multidisciplinar de Investigação Arqueológica (LÂMINA)




Africa[edit]



  • Egypt

    • Conservation Department, Faculty of Archaeology, Cairo University

    • Conservation Department, Faculty of Archaeology, Fayoum University



  • South Africa
    • The South African Institute for Heritage Science, Twee Riviere, Southern Cape: one-year Postgraduate Diploma in Technical Conservation Studies (architectural stone / paper / metals / ceramics ) www.sainst.org




Australia[edit]


  • The University of Melbourne, Centre for Cultural Materials Conservation


Europe[edit]



  • Austria
    • Universitaet fuer Angewandte Kunst, Wien, Konservierung/Restaurierung von Objekten


  • Belgium
    • Koninklijke Academie voor schone kunsten, Antwerpen, metalen conservatie


  • Croatia

    • Sveučilište u Dubrovniku, konzervacija restauracija metala (BA+MA)

    • Umjetnička akademija u Splitu, Konzervacija restauracija metala (BA+MA)



  • Denmark
    • The Royal Danish Academy of Fine Arts, School of Conservation


  • Czech Republic

    • Konzervování-restaurování uměleckořemeslných děl z kovů, Turnov

    • Restaurování kovů ,Vyšší odborná škola restaurátorská , Písek



  • France

    • Université Panthéon-Sorbonne Paris I, Paris, Conservation and restoration department

    • Institut de Formation des Restaurateurs d’Oeuvres d'Art, Institut National du Patrimoine, Saint-Denis-la-Plaine, Metals conservation



  • Finland
    • Metropolia University of Applied Sciences, Helsinki, objects conservation


  • Germany

    • Roemisch Germanisches Zentralmuseum, Mainz, Ausbildung zum Restaurator des Fachbereischs Archeologie

    • Hochschule fuer Technik und Wirtschaft, Berlin, schwerpunkt Archaeologisch-Historisches Kulturgut

    • Staatlische Akademie der Bildende Kuenste, Stuttgart, Objekt Restaurierung

    • Fachhochschule Potsdam, Metallkonservierung

    • University of Applied Sciences Erfurt, Archäologisches Kulturgut und kunsthandwerkliche Objekte



  • Greece
    • Technological Educational Institution (TEI), Athens


  • Hungary
    • Hungarian Academy of Fine Arts, Budapest, conservation of metalwork and goldsmiths works


  • Italy

    • Instituto Superiore per la Conservazione e il Restauro, Roma

    • Opificio delle Pietre Dure, Firenze



  • Netherlands
    • Universiteit van Amsterdam, Amsterdam, MA metaalrestauratie


  • Poland
    • Nicolaus Copernicus University in Torun, Institute of Fine Art, Department of Conservation and Restoration of Historic and Artistic Works, graduate program, metal conservation


  • Portugal
    • Faculdade de Ciências e Tecnologia da Universidade Nova, Lisboa


  • United Kingdom

    • West Dean College, metalwork conservation

    • University of Sussex, metalwork conservation



  • Spain

    • Universidad de Granada, Grado en conservación y restauración de bienes culturales

    • Escuela Superior de Conservación y Restauración de Bienes Culturales, Madrid, Especialidad de bienes arqueológicos

    • Escuela Superior de Conservación y Restauración de Bienes Culturales, Barcelona, Especialidad de bienes arqueológicos

    • Escuela Superior de Conservación y Restauración de Bienes Culturales, Pontevedra, Especialidad de bienes arqueológicos



  • Switzerland
    • Neuchâtel, Haute Ecole de Conservation-restauration Arc, objects conservation




Ukraine[edit]


  • Lvov Academy of Arts, metals conservation


Russian Federation[edit]



  • Conservation Chair of Saint Petersburg State University, St Petersburg, Russian Federation. Conservation of applied arts, archaeological conservation, scientific examination.

  • Факультет искусства реставрации Московской государственной художественно-промышленной академии им.С. Г. Строганова, Moscow-katedra"Restavraciya hudozhestvennogo metalla" (Conservation of artistic metalwork)



India[edit]


  • National Museum Institute of History of Art, Conservation and Museology (deemed to be university) Ministry of Culture, Government of India, New Delhi


Iran[edit]



  • Art University of Isfahan, Faculty of Conservation, Department for Conservation of Art Objects

  • Tabriz Islamic Art University, Conservation Department

  • Art University of tehran, Faculty of Conservation, Department for Conservation of Art Objects



Pakistan[edit]


  • Hazara University, Mansehra


Quatar[edit]


  • University College London, in partnership with Qatar Foundation and Qatar Museums Authority, Doha, objects conservation


Turkey[edit]



  • İstanbul University, Faculty of Literature Department of Conservation and Restoration of Movable Cultural Property

  • Gazi University, Faculty of Fine Arts, Ankara, conservation department



Jordan[edit]


  • Faculty of Archaeology and Anthropology, Yarmouk University


Further reading[edit]



Essential literature[edit]



  1. Corrosion and metal artifacts : a dialogue between conservators and archaeologists and corrosion scientists, Washington 1977.(online)

  2. Conservation & restoration of metals : proceedings of the symposium held in Edinburgh, 30–31 March 1979., Edinburgh 1979.

  3. Stambolov, T. The corrosion and conservation of metallic antiquities and works of art - a preliminary survey, Amsterdam 1985.

  4. Corrosion inhibitors in conservation: The Proceedings of the conference held by UKIC in association with the Museum of London, London 1985.

  5. Pearson, C. Conservation of Marine Archaeological Objects, London 1987.

  6. Conservation of metal statuary and architectural decoration in open-air exposure : symposium, Paris, 6. - 8. X. 1986 = Conservation des oeuvres d'art et décorations en métal exposées en plein air, Rome 1987.(online)

  7. Agraval,O.P. Conservation of metals in humid climate,Rome/Lucknow 1987.(online)

  8. Townsend, J.H.; Child, R.E. Modern metals in museums, Cardiff 1988.

  9. Metals Conservation: 7th International Restorer Seminar, Veszprem, Veszprem 1989.

  10. Brown, B. ; Burnett, H. ; Chase, W. T. ; Goodway, M., Corrosion and metal artifacts : A dialogue between conservators and archaeologists and corrosion scientists, Houston 1991

  11. METAL 95, Proceedings of International Conference on Metal Conservation, London 1997.

  12. METAL 98, Proceedings of International Conference on Metal Conservation, London 1999.

  13. METAL 01, Proceedings of International Conference on Metal Conservation, Perth 2002.

  14. METAL 04, Proceedings of International Conference on Metal Conservation, Canberra 2005.(online)

  15. METAL 07, Proceedings of International Conference on Metal Conservation, Amsterdam 2007.

  16. METAL 2010, Proceedings of International Conference on Metal Conservation, Charleston 2011.

  17. METAL 2013. Proceedings of Internationsl Conference on Metal Conservation, Edinburgh 2013.

  18. METAL 2016.Proceedings of International Conference on Metal Conservation, New Delhi 2017.

  19. Scott, D.A. Metallography and Microstructure of Ancient and Historic Metals, Santa Monica 1991.(online)

  20. Scott, D.A. Ancient and Historic Metals-Conservation and Scientific Research, Santa Monica 1994.(online)

  21. Scott, D.A. Copper and Bronze in Art-Corrosion, Colorants, Conservation, Los Angeles 2002.

  22. Scott, D.A. Iron and Steel in Art-Corrosion, Colorants, Conservation, London 2009.

  23. Scott, D. A. Ancient Metals: Microstructure and Metallurgy Volume I, Los Angeles 2011.

  24. Scott, D. A. Gold and Platinum Metallurgy of Ancient Colombia and Ecuador.: Ancient Metals: Microstructure and Metallurgy Volume II, Los Angeles 2012.

  25. Scott, D. A. ANCIENT METALS: MICROSTRUCTURE ANDMETALLURGY Volume III CATALOGUE OF ANCIENT COLOMBIAN DATA., Los Angeles 2012.

  26. Scott, D. A. Ancient Metals: Microstructure and Metallurgy Vol. IV: Iron and Steel., Los Angeles 2013.

  27. JAIN KAMAL K., NARAIN Shyam, Iron artifacts history, metallurgy, corrosion and conservation, Delhi, Agam Kala Prakashan, 2009, XXII-165 p.

  28. Selwyn, L. Metals and Corrosion-A Handbook for Conservation Professional, Ottawa 2004.

  29. Draymann-Weiser, T. Gilded Metals-History, Technology, Conservation, London 2000.

  30. Draymann-Weiser, T. Dialogue/89 - The conservation of bronze sculpture in the outdoor environment : a dialogue among conservators, curators, environmental scientists, and corrosion engineers, Houston 1992.

  31. Dillman, P.; Beranger, G.; Piccardo, P.; Matthiesen, H. Corrosion of metallic heritage artefacts-Investigation, Conservation and Prediction of long term behaviour, Cambridge 2007.

  32. Cronyn, J.M. The Elements of Archaeological Conservation, London 1990.

  33. Turner-Walker, G. A Practical Guide to the Care and Conservation of Metals, Taipei 2008.

  34. Rodgers, B. The Archaeologist Manual for Conservation-A Guide to Non-toxic, Minimal Intervention Artifact Stabilization, New York 2004.

  35. Stuart, B. Analytical Techniques in Materials Conservation, Chichester 2007.

  36. May, E.; Jones, M. Conservation Science-Heritage Materials, Cambridge 2006.

  37. Untracht, O. Metal Techniques for Craftsmen, New York 1968.

  38. La Niece, S.; Craddock, P. Metal Plating and Patination: Cultural, Technical and Historical Developments, Boston 1993.

  39. Anheuser, K.; Werner, C. (Eds.) Medieval Reliquary Shrines and Precious Metalwork / Châsses-reliquaires et Orfèvrerie Médiévales, London 2006.

  40. Horie, C.V. Materials for Conservation, Oxford 2010.

  41. Smith, R.D. Make all sure : the conservation and restoration of arms and armour, Leeds 2006.

  42. Appelbaum, B. Conservation Treatment Methodology, New York 2007.

  43. Practical Building Conservation!Metals and Glass, Farnham 2012.

  44. Dillmann, P., Watkinson, D., Angelini, E., Adriaens, A., (Ed.) Corrosion and conservation of cultural heritage metallic artefacts, Cambridge 2013.

  45. Risser, E.; Saunders, D. The Restoration of Ancient Bronzes - Naples and Beyond, Los Angeles 2013.(online)

  46. Ghoniem, M.A. Corrosion Inhibitors For Archaeological Copper – Conception, Mechanism and Testing, Saarbrücken 2012.

  47. Yu.J.;Lee.H.;Go.I. Conservation of metal objects,Daejeon 2012.



Some important books on metal conservation in languages other than English[edit]


1.Mourey, W. La conservation des antiquités métalliques, du chantier de fouilles au musée, Draguignan 1987.


2. Stambolov, T.; Bleck, R.D.; Eichelmann, N. Korrosion und Konservierung von Kunst und Kulturgut aus Metall, Weimar I/1987. (online), II/1988. (online)


3. Шемаханская, М.С. РЕСТАВРАЦИЯ МЕТАЛЛА. Методические рекомендации (1989), Moscow 1989. (online)


4. Никитин, М.К., Мельникова,Е.П. ХИМИЯ В РЕСТАВРАЦИИ. СПРАВОЧНОЕ ПОСОБИЕ.; Leningrad 1990 (chapter on metals conservation) (online)


5. Born, H. Restaurierung Antike Bronzewaffen, Mainz 1993.


6. Heinrich, P. (Hrsg.) Metallrestaurierung, Munich 1994.


7. Catello, C. Argenti antichi : tecnologia restauro conservazione : rifacimenti e falsificazioni, Naples 1994.


8. Marabelli, M. Conservazione e restauro dei metalli d`arte, Rome 1995.


9. Krause, J. Sarkofagi cynowe : problematyka technologiczna warsztatowa i konserwatorska, Torun 1995.


10. Dolcini, L. Il restauro delle oreficerie: aggiornamenti, Milan 1996.


11. Mach, M. Metallrestaurierung/Metal Restoration, Munich 1997.(online)


12. Fischer, A. Reste von organischen Materialien an Bodenfunden aus Metall – Identifizierung und Erhaltung für die archäologische Forschung, Munich 1997.


13. Minzhulin, O.I. Restavraciya tvoriv z metalu, Kiev 1998.


14. Anna Grelle Iusco: Matrici metalliche incise. Il problema della conservazione e restauro dalla calcografia romana all'Istituto nazionale per la grafica,Roma 1998.


15.Anheuser, K. Im Feuer Vergoldet, AdR-Schriftenreihe zur Restaurierung und Grabungstechnik, Band 4 / 1998.


16.Mach, M.; Moetnner, P. Zinkguß, die Konservierung von Denkmälern aus Zink, Munich 1999.


17.Barrandon, J.N.; Meyer-Roudet, H. A la recherche du métal perdu : nouvelles technologies dans la restauration des métaux archéologiques, Paris 1999.


18.Meissner, B.; Doktor, A.; Mach, M. Bronze und Galvanoplastik-Geschichte-Materialanalyse-Restaurierung, Dresden 2000. (online)


19.Volfovsky, C.; Philippon, J. La Conservation des metaux, Paris 2001.


20.Brueggerhoff, S.; Koenigfeld, P. Farbige Eisengitter der Barockzeit: Beiträge zu Geschichte und Funktion, Korrosion und Konservierung, Bochum 2002.


21.Melucca Vaccaro, A.; De Palma, G. I Bronzi di Riace : restauro come conoscenza : 1: archeologia, restauro, conservazione/vol.1, Roma 2003.


22.Gaomez Moral, F. Conservacion De Metales De Interes Cultural, Quito 2004.


23.Letardi, P.; Trentin, I.; Cutugno, G. Monumenti in bronzo all'aperto. Esperienze di conservazione e confronto., Genova 2004.


24.Ronald Gobiet (Ed.), Die Salzburger Mariensäule - Zur Konservierung monumentaler Bleiplastiken / Sulla conservazione dei monumenti in piombo, Salzburg 2006.


25. Salvi, A. Meteo e metalli. Conservazione e restauro delle sculture al aperto. Dal Perseo all arte contemporanea, Florence 2007.


26. S. Siano (a cura di): Pulitura laser di bronzi dorati e argenti,Florence 2008.


27.Catello, D Il restauro delle opere in argento. Restoration of silver artifacts, Naples 2008.


28.Schlaepfer, B.R. Metais: Restauracao e conservacao, Rio de Janeiro 2009.


29.Barrio, J.; Cano, E. (Editores). MetalEspaña ’08. Congreso de Conservación y Restauración del Patrimonio Metálico. UAM-CSIC, Madrid 2009.


30. Krist, G. Metallrestaurierung-Metallkonservierung: Geschichte, Methode und Praxis, Vienna 2009.


31.Safarzynski, S.; Weker, W. Wprowadzenie do sztuki konserwacji metalu, Warsaw 2010.


32. Schmidt-Ott, K. Das Plasma in der Metallkonservierung-Moeglichkeiten und Grenzen, Zurich 2010.(online)


33.Bruecke, D. Die Konservierung pigmentierter Altbeschichtungen auf Stahlbauten, Saarbrücken 2011.


34. Diaz Martinez, S.; Garcia Alonso, E. Tecnicas metodologicas applicadas a conservacion-restauracion del patrimonio metalico, Madrid 2011. (online)


35. Barrio Martin, J.; Chamon Frenandez, J. Proyecto Dorados: tecnología, conservación y restauración de los metales dorados medievales, Madrid 2011.


36. La técnica radiográafica en los metales históricos (English translation included), Madrid 2011. (online)


37.Konzervování a restaurování kovů. Ochrana předmětů kulturního dědictví z kovů a jejich slitin, Brno 2011.


38.Knaut, M.; Jeberien, A. (Hrsg.): Adel verpflichtet - Forschungen und Ergebnisse zur Konservierung und Restaurierung der barockzeitlichen Särge vom Schlossplatz Berlin-Mitte, Berlin 2012.


39.Conservation of Metal Objects, National Research Institute of Cultural Heritage, Daejeon (S. Korea)2012.


40.Schmutzler, B. Rettung vor dem Rost, Rahden 2012.


41. Landesamt f. Denkmalpfl. u. Archäologie Sachsen-Anhalt (Hrsg.):Die Merseburger Fürstengruft Geschichte, Zeremoniell, Restaurierung, Halle 2013.


42. Kuhn, H.; Emerling, E. Werke aus Kupfer, Bronze und Messing, Muenchen 2014.


43.Projecto Coremans :Criterios de intervención
en materiales metálicos/Intervention criteria for
metallic materials, Madrid 2015.(online)


44.Krack,E. Konservierungswissenschaft schreibt Geschichte Objektrestaurierung an der Angewandten – Ein Beitrag zur Entwicklungsgeschichte der Konservierungs - wissenschaft und Restaurierung,Wien 2012.
(online)


45.Berger,D. Bronzezeitliche Färbetechniken an Metallobjekten nördlich der Alpen,Halle 2012.(online)


46. Аверин ,А. В. «Реставрация древних металлических изделий»,Moscow 2011.


47. Horev,V. Antikvarnoe oruzhie,ekspertiza i restavratsiya,Rostov on Don 2011.


48. Vančevska,D., Bozaroska Pavlovska,B. Konzervacija na metalni arheološki predmeti,Skopje 2013.


49.Clerbois,S. La conservation-restauration des métaux archéologiques :des premiers soins à la conservation durable , Liege 2015.



Important older books and articles[edit]



  1. Voss, A. Merkbuch, Altertümer auszugraben und auszibewahren. Eine Anleitung für das Verfahren bei Ausgrabungen, sowie zum Konserviren vor- und frühgeschicht Alterthümer. Greg. auf Veranlassung des Hrn. Ministers der geistl., Unterrichts- und Medizinal Angelegenbeiten. Berlin: Mittler und Sohn, 1888.

  2. Rathgen, F. “Über eine neue Anwendung des elektrischen Stromes zur Konservierung antiker Bronzen.” Prometheus1 (1889): pp. 196–198.

  3. Rathgen, F. “Über Konservierung antiker Bronzen.” Dingler's Polytechnisches Journal7 (1896): pp. 44–45.

  4. Rathgen, F. “Über Reinigung oxydirter antiker Kupfermünzen.” Dingler's Polytechnisches Journal7 (1896): pp. 45–46.

  5. Rathgen, F. “Zapon und seine Verwendung zur Konservierung von Sammlungsgegenständen (Handschriften, Wachssiegel, Gipsabgüsse, Stein und Ton, Glas, Metall).” Prometheus 15 (1903/1904): pp. 485–487, 499–502.

  6. Rathgen, F.“Über die Erhalting von Altertumsfunden aus Metall.” P, Mainz, 1904.

  7. Rhousopoloulos, O.A. “Über die Reinigung und Konservierung der Antiquitäten.” Chemische Zeitschrift2 (1903): pp. 202–204.

  8. Berthelot, M. “Sur l'altération lente des objets de cuivre, au sein de la terre et dans les musées.” Comptes Rendus Hebdomadaires des Scéances de l'Académie des Sciences118 (Paris, 1894): pp. 768–770.

  9. Berthelot, M. “Étude sur les métaux qui composent les objets de cuivre de bronze, d'étain, d'or et d'argent, découverts par M. DeMorgan, dans les fouilles de Dahchour, or provenant du Musée de Gizeh.” Annales de Chimie et de Physique, series 7, 4 (1895): pp. 546–574.

  10. Berthelot, M. “Réaction des chlorures alcalins sur l'argent.” Annales de Chimie et de Physique, series 7, 14 (1898): pp. 205–206.

  11. Berthelot, M. “Sur l'altération lente des alliages métalliques contenant du cuivre, au contact simultané de l'air et des chlorures alcalins.” Annales de Chimie et de Physique, series 7, 22 (1901): p. 457–460.

  12. Applegren, H. “Krefting's Methode für Reinigung und Konservierung von Metalgegenständen.” Finska förnminnesföreningens Tidskrift17 (1897): pp. 333–347.

  13. Frazer, W. “Ulcerative Disease of Bronze, or 'Bronze Cancroid.'.” Journal of the Royal Society of Antiquaries of Ireland8 (1898): pp. 61–62.

  14. Setlick, B. “Über natürliche und künstlicheunstliche Patina, sowie Reinigung und Konservierung von Altertümern.” Chemiker-Zeitung 27 (1903): pp. 454–455.

  15. Flinders Petrie, W. M.“The Treatment of Small Antiquities.” Archaeological Journal 65 (1888): pp. 85–89.

  16. Rathgen, F. Die Konservierung von Altertumsfunden, Berlin 1898 (chapter on metals conservation). (English edition online)

  17. Flinders Petrie, W.M. The Method and Aims in Archaeology, London 1904 (chapter on conservation) (online)

  18. Rosenberg, G. Antiquités en fer et en bronze : leur transformation dans la terre contenant de l'acide carbonique et des chlorures et leur conservation, Copenhagen 1917.

  19. Scott, A. The cleaning and restoration of museum exhibits (report upon investigation conducted at the British Museum, Department of Scientific and Industrial Research). London 1921.

  20. Scott, A. The cleaning and restoration of museum exhibits, 2d report. British Museum, Department of Scientific and Industrial Research. London 1923.

  21. Fink, C.G.; Eldridge, C.H. The restoration of ancient bronzes and other alloys, New York 1925.(online)

  22. Galnbek, I.A. Ochistka i sokhranenie metallicheskikh predmetov drevnosti, Leningrad 1925 (first book dedicated to metals conservation/not only bronze and iron)

  23. Scott, A. The cleaning and restoration of museum exhibits, 3d report. British Museum, Department of Scientific and Industrial Research. London 1926.(Russian edition online)

  24. Nichols, H. W. Restoration of ancient bronzes and cure of malignant patina. Chicago 1930. (online)

  25. Lucas, A. Antiques: Their restoration and preservation. London 1932. (online)

  26. Plenderleith, H.J. The preservation of Antiquities, London 1934 (Chapter on metals conservation)

  27. Ocherki po metodike tehnologicheskog issledovaniya restavracii i konservacii drevnih metalicheskih izdeliy, Moscow 1935. (online)

  28. Farmakovskiy, M.V. Konservaciya i restavraciya muzeinih kollekciy, Moscow 1946 (chapter on metals conservation) (online)

  29. Plenderleith, H.J. The Conservation of Antiquities and Works of Art, London 1956 (chapter on metals conservation) (online)

  30. Mazanetz,G. Erhaltung und Wiederherstellung von Bodenfunden.


Bronze, Eisen, Gold, Silber, Blei, Zinn,Wien 1960.



  1. France-Lanord, A. La conservation des antiquites metalliques, Paris 1962.

  2. Pelikan.J.B.,Čupr,V. Zaklady konzervace kovu v muzeich,Prague 1963.

  3. Сообщения ВЦНИЛКР. № 13. - М. 1964 (Сообщения ВЦНИЛКР. № 13. - М. 1964(online))



Articles on metals conservation(gold,tin and pewter,lead,zinc and aluminium)[edit]




Gold[edit]



  • Martin, M.F.T. The technology and conservation of gold and silver in antique jewellery, University of London. Institute of Archaeology, London 1965.

  • Scott, D. A. 1983. The Deterioration of Gold Alloys and Some Aspects of their Conservation. Studies in Conservation 28 (4):194-203 (online)

  • INTERPRETATION OF ANCIENT ARTISTRY: CONSERVATION OF A GOLD WREATH FROM THE FOURTH CENTURY B.C.,JEFFREY P. MAISH (online)

  • Hockey, M. 2001. Approaches to the Conservation of Gold at the British Museum. In Metal 2001: Proceedings of the ICOM Committee for Conservation Metals Working Group: ICOM, 263-269.

  • Hamilton,D. Gold and Gold Alloy Conservation (online)

  • Sian Tiley-Nel, Hazel Botha :The conservation of the Mapungubwe gold collection, South Africa (online)

  • Bolańos Borrero, M.P.F. : "Orfčvrerie: recommandations pour sa conservation"


, Metal 95: Proceedings of the international conference on metals conservation, Semur-en-Auxois, 25–28 September 1995 = Metal 95: actes de la conférence internationale sur la conservation des métaux, Semur-en-Auxois, 25–28 septembre 1995



  • Theile, Johanna María; et alii: "Análisis y conservación de los vasos de oro del Museo Arqueológico Gustavo Le Paige de San Pedro de Atacama, Metal 2001: proceedings of the international conference on metals conservation, Santiago, Chile, 2–6 April 2001

  • Малкиель И.K. Реставрация золотого эгрета с плюмажем,Культурное наследие: сохранение, реставрация, реновация (Материалы семинара «Проблемы реставрации и обеспечения сохранности памятников культуры и истории» - 2011) СПб., 2012

  • Viegas Wesolowska, C. Conservation of a Jewelled Bouquet, V&A Conservation Journal


2006/ 54



Tin and pewter[edit]


  • H.J. Plenderleith, R.M. Organ, The decay and conservation of

museum objects of tin, Studies in Conservation 2 (1953) 63–72.


  • C. Worth, D.H. Keith, On the treatment of Pewter plates from the

Wreck of La Belle, 1686, The International Journal of Nautical
Archaeology 26 (1) (1997) 65–74.



  • Macleod, Ian D.; Wozniak, R. "Corrosion and conservation of tin and pewter from sea water" , Metal 95: Proceedings of the international conference on metals conservation, Semur-en-Auxois, 25-28 September 1995 = Metal 95: actes de la conférence internationale sur la conservation des métaux, Semur-en-Auxois, 25-28 septembre 1995

  • Mottner,P.:Denkmäler aus Blei, Zinn und Zink,Materialforschung, Restaurierung, Konservierung,članak u Metallrestaurierung,Muenchen 1997.(online)

  • Care and conservation of Pewter (online)

  • The Decay and Conservation of Museum Objects of Tin (online)

  • Vak, Bettina, "Zur Restaurierung von vier Giessfässern aus Zinn",Schriften des Vorarlberger Landesmuseums. Reihe B: Kunstgeschichte und Denkmalpflege, Bregenz 1988.

  • Heller, Don B.; Fennimore, Donald L. "The restoration of a William Will pewter teapot" ,Preprints of papers presented at the fifth annual meeting of the AIC, Boston, Mass., 30 May - 2 June 1977

  • Houska, I., Zapalkova, H.: Restaurování cínové sochařské výzdoby


náhrobku olomouckého biskupa Leopolda Egkha z chrámu sv. Mořice v Kroměříži. In Sborník z konference konzervátorů a restaurátorů. Brno 2004, s. 110-114.



Zinc[edit]



  • Mottner,P.:Denkmäler aus Blei, Zinn und Zink,Materialforschung, Restaurierung, Konservierung,članak u Metallrestaurierung,Muenchen 1997.(online)

  • Mottner, P.; Brückner, H.; Freitag, J. : "Conservation of cast zinc sculptures in outdoor exposure, Metal 95: Proceedings of the international conference on metals conservation, Semur-en-Auxois, 25–28 September 1995 = Metal 95: actes de la conférence internationale sur la conservation des métaux, Semur-en-Auxois, 25–28 septembre 1995

  • Care of Objects Made of Zinc - Canadian Conservation Institute (CCI) Notes 9/9 (online)

  • THE CONSERVATION OF AMERICAN WAR MEMORIALS MADE OF ZINC ,CAROL A. GRISSOM, & RONALD S. HARVEY (online)

  • Zappala, Antonio, “Pulizia dai prodotti di corrosione delle matrici calcografiche


di zinco”, KERMES, arte e técnica del restauro, Nardini editore, anno III. 1990 –
8 – (18-26).


  • Alonso, Mercedes; Borrós Salvador y Esteve, Joan “Método para la

restauración de planchas calcográficas de cinc mediante la técnica de plasma frío”
en Goya, revista de arte, 283-284 (2001), 308-313.


  • C. Cugat, Conservación de laminas calcográficas de zinc, Barcelona, 1992,

Departament de Ciencia de Materials i Enginyeria Metal·lurgica. Universidad
Politécnica de Cataluña.



Lead[edit]



  • Organ, R.M., (1953). Use of ion-exchange resin in the tratment of lead objects, Museums Journal,53, 49-52.

  • Lane, H., (1979). Some comparisons of lead conservation methods, including consolidative reduction. In SSCR (eds), The Conservation and Restoration of Metals, 50-60. (Edinburg)

  • Nosek, E.M., (1985). The investigation and conservation of a lead paten from the eleventh century,Studies in Conservation, 30, 19-22.

  • Green, L., (1989). A re-evaluation of lead conservation techniques at the British Museum,Conservation of Metals. In Jaro, M., Veszprem, (eds), p. 121.

  • Mottner,P.:Denkmäler aus Blei, Zinn und Zink,Materialforschung, Restaurierung, Konservierung,članak u Metallrestaurierung,Muenchen 1997.(online)

  • Treatments of Corroded Lead Artefacts AN OVERVIEW, Bart Schotte and Annemie Adriaens (online)

  • Fontaine,C.:Traitement localisé des produits de corrosion du plomb d’une bulle papale attachée à son parchemin (online)

  • CARRADICE, I. A., CAMPBELL, S. A. “The conservation of lead comunion tokens


by potentiostatic reduction”, Studies in Conservation, 39,(1994),100-105


  • DEGRIGNY, C. Y LE GALL, R. “Conservation of ancient lead artefacts corroded in

organic acid environments: electrolytic stabilization/consolidation”, Studies in
Conservation, 44,(1999),157-169.



  • INVESTIGACIÓN SOBRE EL PROCESO DE ESTABILIZACIÓN Y LIMPIEZA POR REDUCCIÓN POTENCIOSTÁTICA DE UN PLOMO EPIGRÁFICO ROMANO - J.Barrio, E. Cano*, M. Arrroyo, A.I. Pardo, y J. Chamón (online)

  • Rocca, E., Rapin, C., Mirambet, F., (2004). Inhibition treatment of the corrosion lead artefacts in atmospheric conditions and by acetic acid vapour: use of sodium decanoate, Corrosion Science, 46,653-665.



Aluminium[edit]


  • Timmons, Sharon, ed., "Aluminum," in Preservation and Conservation:

Principles and Practices, Proceedings of the North American
International Regional Conference, Williamsburg, Virginia and
Philadelphia, Pennsylvania, September 10–16, (Washington, DC:
Smithsonian Institution Press, 1972) pp. 221–222.



  • Stabilization of a wrecked and corroded aluminium aircraft, by G.T. Bailey (online)

  • STABILIZATION OF CORRODED ALUMINIUM,lan D. MacLeod (online)

  • Degrigny, C., Stabilisation de moteurs d´avions immergés, Studies in


Conservation, 40 (1995) 10-18


  • Degrigny, C., La mise au point d’un traitement cathodique de stabilisation de

vestiges aéronautiques immergés en alliages d’aluminium, actes du colloque
Sauvegarder le XXème siècle : la conservation des matériaux modernes, Ottawa
1991, Pub. ICC, (1993), 373-380



  • Adams, C.,Hallam,D. Finishes on aluminium: a conservation perspective,Symposium'91: saving the twentieth century; Ottawa 1993.

  • Hallam, D.; Adams, C.D.; Bailey, G.; Heath, G.A."Redefining the electrochemical treatment of historic aluminium objects", Metal 95: Proceedings of the international conference on metals conservation, Semur-en-Auxois, 25–28 September 1995 = Metal 95: actes de la conférence internationale sur la conservation des métaux, Semur-en-Auxois, 25–28 septembre 1995

  • Larson,J. ,The laser cleaning of an aluminium sculpture,article in The conservation of modern sculpture,Tate Gallery Conference,London 1995.

  • Топильская И.В. Консервация скульптуры из алюминия и его сплавов, хранящейся на открытом воздухе,Художественное наследие. Хранение, исследование, реставрация. № 5. М.ГосНИИР, 1979

  • Sanz,I.C. Aluminio. Duraluminio: patologías y posibles tratamientos de estabilización y restauración, IV Congreso Latinoamericano


de Conservación y Restauración de Metal,Madrid, del 13 al 17 de septiembre de 2011



Online magazines[edit]


  • BROMEC Bulletin of Research on Metal Conservation


Metals conservation blogs[edit]


1.Armas protohistóricas con magnetita, by Jesús Alonso López


2.Conservation of metals - by Catia Viegas-Wesolowska


3.Staffordshire Hoard Blog


4.Cheapside Hoard Blog


5.Silver linings: conserving The Borghese traveling service


6.Zinnrestauration



Free software that can be used for metals conservation[edit]



  1. The Use of Expert Systems in Conservation

  2. The Modular Cleaning Program

  3. Download free conservators documentation software

  4. Freecorp-simple corrosion prediction software

  5. Online Cellular Automata-based corrosion simulation

  6. DiscoveryMat software

  7. ACORN (A COnservation Records Network)



See also[edit]



  • Conservation and restoration of outdoor bronze artworks

  • Conservation and restoration of copper-based objects

  • Conservation and restoration of ferrous objects

  • Conservation and restoration of glass objects

  • Conservation and restoration of ivory objects

  • Conservation and restoration of ceramic objects

  • Conservation and restoration of silver objects



References[edit]





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  2. ^
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    ISBN 978-967-5417-48-1



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External links[edit]



Articles and presentations[edit]



  1. ICOM CC WG Metals

  2. BROMEC - Bulletin of Research On Metal Conservation


  3. METALConsninfo (Metals Conservation Catalog subpage - including big collection of links //300 links!!!//)

  4. ICON Metals Group

  5. Коррозионные разрушения археологического железа и методы его стабилизации

  6. MEDAL project

  7. UCLA metals course-archived presentations

  8. Society for Historical Archaeology-Conservation FAQ and facts

  9. Building Conservation-articles on metals conservation

  10. Development and Testing of Organic Coatings for the Protection of Outdoor Bronze Sculpture from Air-Pollutant Enhanced Corrosion – Year (2001-09)

  11. Development and Testing of Organic Coatings for the Protection of Outdoor Bronze Sculpture from Air-Pollutant Enhanced Corrosion – Year 2 (2001-08)

  12. Development and Testing of Organic Coatings for the Preservation of Outdoor Bronze Sculpture from Air-Pollutant Enhanced Corrosion – Year 3 (2002-18)

  13. Development and Evaluation of Removable Protective Coatings on Bronze (2004-27)

  14. Research Into Protective Coating Systems for Outdoor Bronze Sculpture and Ornamentation Phase I (1997-03)

  15. Research into Protective Coating Systems for Outdoor Bronze Sculpture and Ornamentation Phase II (1999-23)

  16. Research into Protective Coating Systems for Outdoor Bronze Sculpture and Ornamentation Phase III (2000-08)

  17. R.W. Hoge: Conservation Rules for Coins and Medals

  18. A Framework for Conservation of metals

  19. Recognizing Metals and their Corrosion Products

  20. Schotte, B. Adriaens, A. Treatments of Corroded Lead Artefacts - An Overview

  21. A Simple Guide for Archaeological Materials Characterization

  22. Russian article on tannin-based treatment of "bronze disease" (in Russian - Try Google Translator, it is free)

  23. CONSIST project

  24. Hamilton, D. Methods of Conserving Archaeological Material from Underwater Sites

  25. Native American Jewelry Conservation Project: Part 2

  26. Siano, S. Laser Ablation in Conservation of Artworks

  27. CCI Notes 9/2 Storage of Metals

  28. CCI Notes 9/1 Recognizing Active Corrosion

  29. CCI Notes 9/4 Basic Care of Coins and Medals

  30. Watkinson, D. Preservation of Metallic Cultural Heritage,2010.

  31. Boissonnas, V. An introduction to the history of metals conservation

  32. Preservapedia - Metals conservation

  33. Grissom, C.A. The Conservation of American War Memorials Made of Zinc

  34. Bailey, G.T. Stabilization of wrecked and corroded aluminium aircraft

  35. CCI Notes 9/3 The Cleaning, Polishing and Protective Waxing of Brass and Copper

  36. CCI Silver Care and Tarnish removal

  37. CCI Notes 9/8 Mechanical Removal of Rust from Machined Ferrous Surfaces

  38. CCI Notes 9/5 Tannic Acid Treatment

  39. Care and Conservation of Pewter

  40. Conservation of lead sculpture

  41. Conservation of lead, tin and lead alloys

  42. Watkinson, D. Conserving cultural material : Ethical challenges for the conservator

  43. Minimum Common Standards Definition – Model Curricula Metals -EQF Level 7 - ECPL

  44. Laboratorie d archeologie des metaux, Nancy

  45. The TIGHAR Guide to Aviation Historic Preservation Terminology

  46. Hayha, H. THE HISTORY OF IRON PROTECTION. DESCRIPTION OF MATERIALS AND EVALUATION OF THEIR PROPERTIES

  47. National Research Laboratory for Conservation of Cultural Property, Lucknow, India-research papers, some good articles on metals conservation

  48. Care and Handling of Bronze Objects

  49. Wanhill, R.J.H. Brittle archaeological silver- identification, restoration and conservation

  50. Conservation of iron and steelwork in historic structures and machinery/Maintenance handbook

  51. Finishing Techniques in Metalwork

  52. AIC Metals Conservation wiki

  53. Care of Objects Made of Zinc

  54. Aircraft Restoration Practice and Philosophy

  55. The France-Lanord collection

  56. Funcionalidad vs conservacion en piezas de orfebreria...

  57. Creating a microclimate box for metal storage

  58. Identifying Archaeological Metal

  59. Conservation Case Studies: A medieval tabernacle from Cologne

  60. Cleaning treatment of a tarnished Daguerreotype by using the reducing afterglow of an atmospheric plasma

  61. Plazmochemické procesy a technologie pro konzervaci kovových archeologických předmětů

  62. Protection of metal artifacts with the formation of metal–oxalates complexes by Beauveria bassiana

  63. The Croatian Apoxyomenos

  64. Серебряный кратир из Новгорода отреставрируют лазером

  65. Guidelines for the Storage and Display of Archaeological Metalwork

  66. NHIG Conservation Principles for Heritage Forged and Cast Ironwork

  67. An ABS Recycled Coating for Corrosion Protection and Conservation of Copper and Alloys of Cultural or Historic Value

  68. PLECO - an innovative electrolytic pencil for the localised cleaning of tarnished silver



Download free books[edit]



  1. Metallography and Microstructure of Ancient and Historic Metals

  2. Ancient and Historic Metals-Conservation and Scientific Research

  3. Metals in America's Historic Buildings - Uses and Preservation Treatments

  4. Diaz Martinez, S.; Garcia Alonso, E. Tecnicas metodologicas aplicadas a la conservacion-restauracion del patrimonio metalico, Madrid 2011.

  5. La técnica radiográafica en los metales históricos (English translation included), Madrid 2011.

  6. Mach, M.; Doktor, A.; Meissner, B. Bronze und Galvanoplastik-Geschichte-Materialanlyse-Restaurierung, Dresden 2001.

  7. РЕСТАВРАЦИЯ МЕТАЛЛА. Методические рекомендации (1989)(in Russian – try Google translator – it is free, translation can be very silly)

  8. El Relicario de santa Lucia:Restauracion, analisis y estudio Historico-artistico

  9. Katharina Schmidt-Ott Das Plasma in Der metAll Konservierung– mögliChKeiten unD grenzen

  10. Ligas metálicas : Investigação e conservação

  11. Stambolov, T.;Bleck, R.D.;Eichelmann, N. Korrosion und Konservierung von Kunst und Kulturgut aus Metall/I(1987.)

  12. Stambolov, T.;Bleck, R.D.; Eichelmann, N. Korrosion und Konservierung von Kunst und Kulturgut aus Metall/II(1988.)

  13. Proyecto Coremans. Criterios de intervención en materiales metálicos

  14. Turner Walker,G. A Practical Guide to the Care and Conservation of Metals(2008.)



Download free conference proceedings[edit]



  1. Archaeological Iron Conservation Colloquium 2010 Abstracts/1

  2. Archaeological Iron Conservation Colloquium 2010 Abstracts /2

  3. Archaeological Iron Conservation Colloquium 2010 Abstracts /3

  4. Archaeological Iron Conservation Colloquium 2010 Abstracts/4

  5. Archaeological Iron Conservation Colloquium 2010 Abstracts/posters

  6. Bronze colloquium 2012. conference brochure

  7. Anais 2. Congresso Latino-americano de restauracao de metais, Rio de Janeiro 2005.

  8. IV Congreso Latinoamericano de Conservación y Restauración de Metal

  9. METAL 2004-proceedings of conference

  10. Incredible Industry

  11. METAL 2010. proceedings



  1. Extended Abstracts ENAMEL 2010

  2. 4th Biennial Experts’ Meeting on Enamel on Metal Conservation, Barcelona 2012.

  3. Lets Putz Silber 2014.

  4. History, Technology and Conservation of Ancient Metals, Glasses and Enamels

  5. Actas del II Congreso de Conservación y Restauración del Patrimonio Metálico. MetalEspaña 2015



Download free theses[edit]



  1. Folgado Martins, M. La practica de la limpieza con laser en materiales metalicos - hierro, cobre, plata

  2. Marušić, K. Protection of patinated bronze by non toxic inhibitors, thesis, Zagreb 2010.

  3. Strandberg, H. Perspectives on Bronze Sculpture Conservation. Modelling Copper and Bronze Corrosion, thesis

  4. Lage de la Rosa,M. Caracterización del zinc calcográfico contemporáneo para su conservación y restauración.

  5. L.B. Brostoff: Coating Strategies for the Protection of Outdoor Bronze Art and Ornamentation (thesis)

  6. Regis Bertholon: La limite de la surface d origine des objets metalliques archeologiques - doctoral thesis

  7. Castillo Narrea, L.E.J.A. Conservacion y Restauracion de algunos objetos arqueologicos: Arte, Tecnica y Metalurgia, Santiago de Chile 2008. - thesis

  8. Koh, Y.S. Laser Cleaning as a Conservation Technique for Corroded Metal Artifacts, doctoral thesis, Lulea 2006.

  9. Hollner, S. Development de nouveaux traitements de protection a base d acide carboxylique...

  10. Carrasco, G.L. Preservacao de artefatos ornamentais de ferro integrados a arqitetura...

  11. Saleh, A.M.S. CONSERVATION METHODS OF IRON ARTIFACTS RECOVERED FROM THE MARINE ENVIRONMENT

  12. Rimmer, M.B. Investigating the treatment of chloride-infested archaeological iron objects

  13. Thickett, D. Post Excavation Changes and Preventive Conservation of Archaeological Iron

  14. A study of the electrolitic reduction of corroded lead object and the application, characterization and testing of a protective lead carboxylate coating/ doctoral thesis by Bart Schotte

  15. Cano Diaz, Emilio (2004) Efecto de los vapores de los acidos acetico y formico en la degradacion y patinado del cobre. Thesis PhD.

  16. Alonso Cantalapiedra, Maria de la Paz (2001)Efectos de la contaminacion atmosferica en la esculturas de bronce:estudio de la patina. Thesis PhD.

  17. Valle y Diaz, Felix del (2001) La electroquimica y las poliamidas en la restauracion reversible y a fuego de la orfebreria esmaltada. Thesis PhD.

  18. Kolmanitsch, G. Pflege und Massnahmen Konzept fuer Bronzen in Freien-Am Beispiel des Marc Anton Monuments, Wien -Secession(thesis)

  19. Casanova, M. G. Metales arqueologicos de la costa norte del Peru: Conservacion, Analisis y Restauracion

  20. Rivera Diaz, J. A. Restauracion Y Conservacion De Metales Arqueologicos Submarinos:Plata y bronce

  21. Fox, G.L. Bronze Age Objects from Tel Nami, Israel:Their Conservation and Implications for Ancient Metallurgy in the Eastern Mediterranean

  22. Gujarathi, K. Corrosion of Aluminium Alloy 2024 Belonging to The 1930s in Seawater Environment-thesis(2008.)

  23. Chamon Fernandez, J. Arqueometria, Conservacion y Restauracion de los metales dorados medievales, doctoral thesis

  24. Nunez, G.A.N. Tres casos de restauracion y conservacion de metales arqueologicos, thesis Santiago de Chile 2010.

  25. Garcia, J.M. METODOLOGÍA Y TÉCNICAS DE CONSERVACIÓN DE OBJetos arqueologicos de hierro

  26. Berankova, R. Konzervovane kovovehu artefaktu(železna sekyra)

  27. Einarsdottir, S.S. Mass-conservation of Archaeological Iron Artefacts

  28. Brueck, D. Ermittlung eines pigmentierten Beschichtungssystems zur Konservierung von historischen Stahlbauten bei Erhalt der Altbeschichtung– am Beispiel eines Dachtragwerkes in Hamburg

  29. Pappot, A. Lokale behandeling van bronspest

  30. The Evaluation of Corrosion Inhibitors for Application to Copper and Copper Alloy Archaeological Artefacts by R. Faltermeier

  31. The Formation of Acetate Corrosion on Bronze Antiquities:Characterisation and Conservation by Alice Boccia Paterakis

  32. Desalination of Archaeological Composite Objects Consisting of Wrought Iron and Wood/Bone. With Focus on the Iron Component by Sigridur Thorgeirsdottir

  33. Crawford, J. "Case studies in the determination of the original surface limits of the ferrous armour of the Order of St John, Palace Armoury, Malta"

  34. Pienimäki;A. :Desalination of iron - A comparison of fresh, wet finds and dry, storaged ones.

  35. Lewis,M. The Influence of Atmospheric Moisture on the Corrosion of Chloride-Contaminated Wrought Iron

  36. Grayburn,R.A. Spectroelectrochemical techniques for the conservation of metallic artefacts

  37. Fontaine,C. Traitement electrolytique localise des produits de corrosion du plomb et des alliages du plomb-etain

  38. Development and optimisation of protocols for surface cleaning of Cultural Heritage metals thesis by C. L. Soto Quintana

  39. Rosetti,L. IN SITU NON DESTRUCTIVE MONITORING TECHNIQUES AND PROTECTIVE COATINGS FOR COPPER ALLOYS ARTEFACTS OF CULTURAL HERITAGE

  40. Brambilla,L. MULTIANALYTICAL APPROACH FOR THE STUDY OF BRONZE AND GILDED BRONZE ARTEFACTS

  41. Carrett de Vascvoncelos,M.L. Artefatos em ferro de origem terrestre: um estudo de caso sobre a interface entre pesquisa arqueológica e conservação no sítio Charqueada Santa

  42. Golfomitsou,S. SYNERGISTIC EFFECTS OF ADDITIVES TO BENZOTRIAZOLE SOLUTIONS APPLIED AS CORROSION INHIBITORS TO ARCHAEOLOGICAL COPPER AND COPPER ALLOY ARTEFACTs

  43. Sangouard,E.Testing corrosion inhibitors for the treatment of marine iron/waterlogged wood composite artifacts in polyethylene glycol solutions

  44. Elia,A. Application of electrochemical methods for the study and protection of heritage copper alloys

  45. Kergourlay,F. Étude des mécanismes dedéchloruration d'objets archéologiques ferreux corrodés en milieu marin

  46. Liengme,G. Freilegung archaeologischer Eisenfunde mittels selektiver Hochspannungfragmentierung

  47. Karla Frajerová „Problematika dodržování restaurátorského kodexu při konzervování-restaurování uměleckořemeslných děl z kovů“

  48. Patrick Barta -Průzkum a konzervace železného meče s fixací korozních produktů a organických fragmentů

  49. Karel Rapouch Úprava povrchu letadla MIG-19S pro možnosti konzervace siloxany

  50. Eva Smejkalova Konzervace velkomoravských naušnic

  51. Marquardt, A.E. Novel protective coatings for silver and copper alloy cultural heritage objects using atomic layer deposited metal oxide barrier films

  52. Anja Mihotović Konzervacija i restauracija antičkog kovanog novca s lokaliteta Ivandvor i park kraljice Katarine Kosače

  53. Hahmann,L. Minuten-Rädersonnenuhr aus dem Mathematisch-Physikalischen Salon:Untersuchungen zu schwarzen Verfärbungen auf Vergoldungen- deren Entstehung und Behandlung

  54. Rozalen Alcaraz,C. INHIBICIÓN SOBRE COBRE Y SUS ALEACIONES EN ATMÓSFERAS NO CONTROLADAS, ANÁLISIS CRÍTICO DEL ESTADO DE LA CUESTIÓN

  55. van der Molen,R. Droogijsstralen, Dé Reinigingstechniek Voor Metalen?

  56. van Santen,H. The Cleaning of Sterling Silver with Acidified Thiourea Cleaning Solutions: Solution Recipe Optimization



Metals conservation video files[edit]



  1. Conserving Bronze: The Lamp with Erotes from Vani

  2. Caring for Metals - Housekeeping for Historic Sites

  3. USS Monitor Engine Removed from Water

  4. Laser Cleaning of Bronze Eagle in Oak Park

  5. Re-Constructing Silver Objects from the Staffordshire Hoard

  6. Erik Risser Describes the Conservation of the Apollo Saettante at the Getty Villa

  7. CoinScubber - Cleaning Ancient Coins

  8. Cleaning an Outdoor Sculpture Part I

  9. Dorure au mercure

  10. Fachhochschule Potsdam Metallrestaurierung

  11. Repatination of a Bronze WWII Memorial Plaque

  12. Restoring an Artifact at the SCCRRMM

  13. Clemson Conservation Center: H.L. Hunley submarine - Part 1/3

  14. NCPTT Iron Fence Repair - Cemetery Monument Conservation

  15. Restoration of the USS Monitor

  16. Apoxyomenos de Croacia 5

  17. Bronze Age Fibula

  18. Patina & corrosion surfaces on ancient bronzes

  19. Campanas medievales limpieza criogenica

  20. Restauro David Donatello

  21. Cruz Parroquial de la iglesia de Santa María de la Asunción de Estepa (Sevilla)

  22. Il nuovo intervento di restauro sui Bronzi di Riace

  23. Il restauro della base originale del Cinghiale in Firenze

  24. Restauración y conservación de los cañones de La Sabana

  25. Conservation of iron artefacts at Jamestown

  26. Cleaning the Staffordshire Hoard - K551 and K1775.

  27. Conservation of Henry Moore's bronze sculpture 'Knife Edge Two Piece'

  28. Реставрация художественного металла: эксперимент в профессии

  29. Реставрация металла

  30. Лаборатория научной реставрации драгоценных металлов











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